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- atom:
- Smallest (about 10^-10 m) unit of matter, forming a specific element. It
- consists of:
- - nucleus: Small (about 10000 smaller than atom) but very dense (almost all
- atom weight) area containing nucleons, which are:
- - protons: positively charged particles
- - neutrons: particles without electric charge
- these are held together by nuclear force that overcomes electric force that
- otherwise pushes protons away from each other.
- - electron cloud: Contains electrons (negatively charged particles), that are
- attached to protons via electromagnetic force. The cloud is subdivided into
- shells (layers), which are subdivided into subshells:
- shell subshells max electrons ^ closer to nucleus
- -------------------------------------------- | lower energy
- 1 (K) 1s 2 > 2 = 2 |
-
- 2 (L) 2s 2 \ 2 + 6 = 8
- 2p 6 /
- 3 (M) 3s 2 \
- 3p 6 > 2 + 6 + 10 = 18
- 3d 10 /
- 4 (N) 4s 2 \
- 4p 6 \ ... = 32
- 4d 10 /
- 4f 14 /
- 5 (O) 5s 2 \
- 5p 6 \
- 5d 10 > ... = 50
- 5f 14 /
- 5g 18 /
- ... |
- | higher energy
- v further from nucleus
- The last (furthest) shell occupied by electrons is called valence shell and
- mostly determines chemical properties such as conductivity. Shells are
- filled from the innermost, but not generally -- with the higher ones the
- rule is more complex (so there can be non-filled non-valence shell).
- Each subshell can further take a form of one of possible orbitals, i.e.
- probability "shape" of where the electron can be found. Some subshells, e.g.
- 1s or 2s have only one possible orbital (shape) but others, e.g. 2p, have
- multiple (2px, 2py, 2pz).
- Atom has the same number of protons and electrons and so has a net electric
- charge 0, but can have different number of neutrons, forming different
- isotopes.
- electron configuration: Says the specific placement of electrons in (sub)shells.
- The lowest energy configuration is called a ground state, e.g. 1s^2 2s^2 2p^6
- 3s^1 for sodium, others are called excited states, e.g. 1s^2 2s^2 2p^6 3p^1.
- Transition between configurations consumes or emits energy (photons).
- isotope: Variant of the same atom, differing in number of neutrons (and weight),
- e.g. deuterium (helium with 2 neutrons, so called heavy hydrogen).
- ion: Is formed from an atom or molecule that has different number of electrons
- than protons, giving it either a positive or negative electric charge (e.g.
- after a collision with subatomic particle, radiation etc.).
- molecule: Electrically neutral group of multiple atoms held together by chemical
- bond. E.g. O2, H2O etc.
- chemical bond: Lasting bond that holds atoms together. Some types of bonds are:
- - covalent: Atoms share electrons, mostly electron pairs. Atoms want to fill
- the valent shell fully, so e.g. H2O is formed by O wanting 2 electrons
- (it has 8 electrons total, 2 in first shell, 6 out of 8 possible in the
- second valent shell, missing 2) and each O wants 1 (having 1 of 2 possible
- in the first shell), so they join to satisfy this.
- -
- mole: SI unit of substance amount, means exactly 6.02214076 * 10^23 particles.
- Elements are denoted as:
- Z <--- atomic number, the number of protons, e.g. 1 for hydrogen
- E <--- element name, e.g. H for hydrogen
- M <--- atomic mass (in grams/mole), e.g. 1.00794 for hydrogen
- periodic table of elements:
- Graphical ordering of elements in 2D table, it consists of:
- - groups: columns, there are 18 groups
- - periods: rows, there are 7 periods
- The table shows periodic trends (caused by number of electrons needed to fill
- the s, p, d and f subshells, which mostly determines chemical properties),
- i.e. repeating patterns, e.g.:
- - metalicity: towards bottom-left corner elements are more metalic
- - atomic radius: towards top-right corner elements have bigger atomic radius
- - ionization energy: towards top-right elements have more ionization energy
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