chemistry cheatsheet.txt 4.4 KB

123456789101112131415161718192021222324252627282930313233343536373839404142434445464748495051525354555657585960616263646566676869707172737475767778798081828384858687888990919293949596979899100101102103104105106107108109110111
  1. atom:
  2. Smallest (about 10^-10 m) unit of matter, forming a specific element. It
  3. consists of:
  4. - nucleus: Small (about 10000 smaller than atom) but very dense (almost all
  5. atom weight) area containing nucleons, which are:
  6. - protons: positively charged particles
  7. - neutrons: particles without electric charge
  8. these are held together by nuclear force that overcomes electric force that
  9. otherwise pushes protons away from each other.
  10. - electron cloud: Contains electrons (negatively charged particles), that are
  11. attached to protons via electromagnetic force. The cloud is subdivided into
  12. shells (layers), which are subdivided into subshells:
  13. shell subshells max electrons ^ closer to nucleus
  14. -------------------------------------------- | lower energy
  15. 1 (K) 1s 2 > 2 = 2 |
  16. 2 (L) 2s 2 \ 2 + 6 = 8
  17. 2p 6 /
  18. 3 (M) 3s 2 \
  19. 3p 6 > 2 + 6 + 10 = 18
  20. 3d 10 /
  21. 4 (N) 4s 2 \
  22. 4p 6 \ ... = 32
  23. 4d 10 /
  24. 4f 14 /
  25. 5 (O) 5s 2 \
  26. 5p 6 \
  27. 5d 10 > ... = 50
  28. 5f 14 /
  29. 5g 18 /
  30. ... |
  31. | higher energy
  32. v further from nucleus
  33. The last (furthest) shell occupied by electrons is called valence shell and
  34. mostly determines chemical properties such as conductivity. Shells are
  35. filled from the innermost, but not generally -- with the higher ones the
  36. rule is more complex (so there can be non-filled non-valence shell).
  37. Each subshell can further take a form of one of possible orbitals, i.e.
  38. probability "shape" of where the electron can be found. Some subshells, e.g.
  39. 1s or 2s have only one possible orbital (shape) but others, e.g. 2p, have
  40. multiple (2px, 2py, 2pz).
  41. Atom has the same number of protons and electrons and so has a net electric
  42. charge 0, but can have different number of neutrons, forming different
  43. isotopes.
  44. electron configuration: Says the specific placement of electrons in (sub)shells.
  45. The lowest energy configuration is called a ground state, e.g. 1s^2 2s^2 2p^6
  46. 3s^1 for sodium, others are called excited states, e.g. 1s^2 2s^2 2p^6 3p^1.
  47. Transition between configurations consumes or emits energy (photons).
  48. isotope: Variant of the same atom, differing in number of neutrons (and weight),
  49. e.g. deuterium (helium with 2 neutrons, so called heavy hydrogen).
  50. ion: Is formed from an atom or molecule that has different number of electrons
  51. than protons, giving it either a positive or negative electric charge (e.g.
  52. after a collision with subatomic particle, radiation etc.).
  53. molecule: Electrically neutral group of multiple atoms held together by chemical
  54. bond. E.g. O2, H2O etc.
  55. chemical bond: Lasting bond that holds atoms together. Some types of bonds are:
  56. - covalent: Atoms share electrons, mostly electron pairs. Atoms want to fill
  57. the valent shell fully, so e.g. H2O is formed by O wanting 2 electrons
  58. (it has 8 electrons total, 2 in first shell, 6 out of 8 possible in the
  59. second valent shell, missing 2) and each O wants 1 (having 1 of 2 possible
  60. in the first shell), so they join to satisfy this.
  61. -
  62. mole: SI unit of substance amount, means exactly 6.02214076 * 10^23 particles.
  63. Elements are denoted as:
  64. Z <--- atomic number, the number of protons, e.g. 1 for hydrogen
  65. E <--- element name, e.g. H for hydrogen
  66. M <--- atomic mass (in grams/mole), e.g. 1.00794 for hydrogen
  67. periodic table of elements:
  68. Graphical ordering of elements in 2D table, it consists of:
  69. - groups: columns, there are 18 groups
  70. - periods: rows, there are 7 periods
  71. The table shows periodic trends (caused by number of electrons needed to fill
  72. the s, p, d and f subshells, which mostly determines chemical properties),
  73. i.e. repeating patterns, e.g.:
  74. - metalicity: towards bottom-left corner elements are more metalic
  75. - atomic radius: towards top-right corner elements have bigger atomic radius
  76. - ionization energy: towards top-right elements have more ionization energy